Beilstein J. Org. Chem.2017,13, 2146–2152, doi:10.3762/bjoc.13.213
: highercarbonsugars; reductive amination; sucrose; Introduction
Carbohydrates, because of their availability in a variety of optical pure forms, are particularly useful in planning and executing the synthesis of chiral macrocyclic compounds [1][2][3][4][5]. In this context, polyhydroxylated derivatives
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Graphical Abstract
Figure 1:
Previous synthesis of a C12-higher sugar 1 and its application in the preparation of a polyhydroxyl...
Beilstein J. Org. Chem.2014,10, 1246–1254, doi:10.3762/bjoc.10.124
out that this methodology, which is used in the synthesis of more simple derivatives such as highercarbonsugars, was also applicable for the preparation of the sucrose dimer.
Experimental
General methods
All reported NMR spectra were recorded with a Varian-Vnmrs-600 MHz spectrometer (at 600 and 150